Issue 10, 1982

Connective (C–C) route to hindered epoxides and olefins from hindered ketones

Abstract

Hindered ketones have been transformed into hindered epoxides (5) and olefins (6) with the concomitant formation of new carbon–carbon bonds using β-hydroxyselenides as key intermediates; the unusual reactivity of such crowded molecules is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 564-566

Connective (C–C) route to hindered epoxides and olefins from hindered ketones

D. Labar and A. Krief, J. Chem. Soc., Chem. Commun., 1982, 564 DOI: 10.1039/C39820000564

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