Starting from 3-methylbut-1-yn-3-ol, a short synthesis of αα-dimethylallyltrimethylsilane (a selective prenylation reagent) has been achieved in 47% overall yield; several other unsaturated organosilicon intermediates of wide potential utility in organic synthesis are also prepared.
B. Bennetau, J. Pillot, J. Dunogues and R. Calas, J. Chem. Soc., Chem. Commun., 1981, 1094 DOI: 10.1039/C39810001094
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