Treatment of hetisine with acid leads to two unusual rearrangement products, (3) and (4), via a unique transformation of a dihydroxy-bicyclo [2.2.2]octanee system to an adamantane-type skelleton; the structure of (3) has been determined by X-ray crystallography.
S. W. Pelletier, N. V. Mody, J. F. Moore, A. M. Ateya and L. C. Schramm, J. Chem. Soc., Chem. Commun., 1981, 327 DOI: 10.1039/C39810000327
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