Issue 0, 1980

The preparation and dienone–phenol rearrangement of androsta-2,5-diene-4,17-dione

Abstract

The preparation of androsta-2,5-diene-4,17-dione from dehydroisoandrosterone is described. Its dienone–phenol rearrangement, in the presence of hydrobromic acid and glacial acetic acid, affords 1-methyl-4-hydroxyestra-1,3,5(10)-trin-17-one.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1980, 1311-1313

The preparation and dienone–phenol rearrangement of androsta-2,5-diene-4,17-dione

J. R. Hanson, D. Raines and S. G. Knights, J. Chem. Soc., Perkin Trans. 1, 1980, 1311 DOI: 10.1039/P19800001311

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