Issue 0, 1980

1H nuclear magnetic resonance studies of the hydrolysis of the Be(H2O) 2+4 cation

Abstract

The hydrolysis reaction of Be(H2O)2+4 in concentrated solution has been followed using 1H and 9Be n.m.r. spectroscopy, the former at reduced temperature. The existence of two species in addition to Be(H2O)2+4 is demonstrated and intensity measurements are shown to be in accord with the formulations of the species [Be2(OH)]3+ and (BeOH)3+3 currently preferred on the basis of electrometric studies. The beryllium ion remains in an essentially regular tetrahedral environment in all the species observed.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1980,76, 2212-2220

1 H nuclear magnetic resonance studies of the hydrolysis of the Be(H2O)2+4 cation

J. W. Akitt and R. H. Duncan, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 2212 DOI: 10.1039/F19807602212

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