The formation of the cation radical of methyl viologen was established when an aqueos micellar solution containing haematoporphyrin, methyl viologen and reducing agent was irradiated by visible light and hydrogen evolution was observed on the addition of hydrogenase to the system.
I. Okura and N. K. Thuan, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 2209 DOI: 10.1039/F19807602209
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