The mechanism of the singlet oxygenation of thiones has been studied by using 1,2-benzodithiole-3-thione; the reaction was found to proceed via a sulphine but not a dioxathietan intermediate.
S. Tamagaki and K. Hotta, J. Chem. Soc., Chem. Commun., 1980, 598b DOI: 10.1039/C3980000598B
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