Issue 24, 1980

Evidence for a 1,3-sigmatropic rearrangement of a nitrile N-benzylimide to a C-benzyl-substituted diazoalkane

Abstract

The flash vacuum pyrolysis of N-benzyl-2-phenyl-1,3,4-oxadiazolin-5-one generates a nitrile N-imide which rearranges to a diazoalkane via a 1,3-sigmatropic benzyl shift.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1229-1230

Evidence for a 1,3-sigmatropic rearrangement of a nitrile N-benzylimide to a C-benzyl-substituted diazoalkane

A. Padwa, T. Caruso and D. Plache, J. Chem. Soc., Chem. Commun., 1980, 1229 DOI: 10.1039/C39800001229

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