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Pyrolytic graphite is not intercalated by GeF4 alone but is intercalated by GeF4–F2 mixtures to yield, at the intercalation limit, at 20 °C, a first-stage material, C12GeF5–6, which is in equilibrium with gaseous fluorine.
E. M. McCarron, Y. J. Grannec and N. Bartlett, J. Chem. Soc., Chem. Commun., 1980, 890 DOI: 10.1039/C39800000890
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