Implication of 195Pt chemical shift anisotropy relaxation in n.m.r. studies of platinum complexes
Abstract
A dominant chemical shift anisotropy relaxation mechanism can account, at high magnetic fields, for the disappearance of some of the 195Pt–1H and 195Pt–13C coupling constants and for the line broadening observed in the 195Pt n.m.r. spectra of PtII complexes.