CO2 is formed in small yields in the gas-phase reaction of N2O5 and CO mixtures and the variation with composition precludes the source being the reaction of CO with the known intermediates in N2O5 decomposition; a peroxy-NO3 radical is proposed as the new intermediate with the critical role.
G. J. Audley, D. L. Baulch, I. M. Campbell and L. T. Hamill, J. Chem. Soc., Chem. Commun., 1980, 433 DOI: 10.1039/C39800000433
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