Dialkyl phosphite ions and geminal chloro- or arylsulphonyl-nitroalkanes react by a free radical chain mechanism to form dialkyl α-nitroalkylphosphonates.
G. A. Russell and J. Hershberger, J. Chem. Soc., Chem. Commun., 1980, 216 DOI: 10.1039/C39800000216
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