In trifluoromethanesulphonic acid (HTFMS) the P–N bond of (RO)2P(O)NMe2 is stable, but de-O-alkylation is observed; rates of the oxygen–alkyl cleavage of phosphoramidates and some other phosphoryl compounds in HTFMS have been determined.
T. A. Modro, J. Chem. Soc., Chem. Commun., 1980, 201 DOI: 10.1039/C39800000201
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