Issue 1, 1980

Novel modes for selective protection of ketose sugars and oligosaccharides of biological and industrial importance

Abstract

2-Methoxypropene converts carbohydrates into cyclic isopropylidene acetals under exclusively kinetic control, affording novel, partially protected sugars of value in synthesis; such disaccharides as maltose and lactose react without glycosidic cleavage to give 4′,6′-acetals (on the non-reducing extremity), and lactose also undergoes inter-residue acetonation between O-2′ and O-6.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 21-22

Novel modes for selective protection of ketose sugars and oligosaccharides of biological and industrial importance

E. Fanton, J. Gelas and D. Horton, J. Chem. Soc., Chem. Commun., 1980, 21 DOI: 10.1039/C39800000021

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