The molecular stereochemistry of a haemichrome salt, bis-(3-chloropyridine)octaethylporphinatoiron(III) perchlorate, has been determined; the structural parameters of the co-ordination group are in accord with a spin-equilibrium between two states, S= 1/2 and S= 5/2.
W. R. Scheidt and D. K. Geiger, J. Chem. Soc., Chem. Commun., 1979, 1154 DOI: 10.1039/C39790001154
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