The title compounds, which are derived from the cycloaddition of α-nitroso-acrylic esters or of α-nitrosoacrolein to olefins, are thermally decarboxylated to give γ-hydroxynitriles in a stereoselective process.
T. L. Gilchrist and T. G. Roberts, J. Chem. Soc., Chem. Commun., 1979, 1090 DOI: 10.1039/C39790001090
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