A haemin-containing model system for biological substrate hydroxylation has been studied and direct evidence for participation of both superoxide and hydroperoxide anions in the catalytic process is presented.
P. A. Adams, M. C. Berman and D. A. Baldwin, J. Chem. Soc., Chem. Commun., 1979, 856 DOI: 10.1039/C39790000856
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