A simple regio- and stereo-specific terminal and internal allylic oxidation via benzenesulphenyl chloride addition is reported; using this method racemic nuciferal (11) and ar-turmerone (12) were synthesized from racemic α-curcumene (1a), and racemic ipsdienol (10c) from myrcene (1c).
Y. Masaki, K. Hashimoto, K. Sakuma and K. Kaji, J. Chem. Soc., Chem. Commun., 1979, 855 DOI: 10.1039/C39790000855
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