Issue 19, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

Ligand control of product stereochemistry in the photosubstitution reactions of rhodium(III) ammine complexes. The photoreactions of trans-[Rh(NH3)4(OH)Cl]+

Leif H. Skibsted  and  Peter C. Ford  

Abstract

Ligand field photolysis of tran-[Rh(NH3)4(OH)Cl]+ results in concomitant photohydrolysis–photoisomerization (quantum yield = 0·21 mol einstein–1) to give cis-[Rh(NH3)4(OH)2]+, a stereochemical result in marked contrast to the analogous aquo species, cis- and trans-[Rh(NH3)4(H2O)Cl]2+, which undergo cis to trans but not trans to cis photoisomerization nor chloride photolabilization.

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Article information

DOI
https://doi.org/10.1039/C39790000853
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 853-854

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Ligand control of product stereochemistry in the photosubstitution reactions of rhodium(III) ammine complexes. The photoreactions of trans-[Rh(NH3)4(OH)Cl]+

L. H. Skibsted and P. C. Ford, J. Chem. Soc., Chem. Commun., 1979, 853 DOI: 10.1039/C39790000853

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