Increasing substitution of the comonomer in high-pressure, free-radical copolymerizations of maleic anhydride with multisubstituted olefins involves greater pressure acceleration and hence more negative activation volumes and later transition states.
G. Jenner and M. Kellou, J. Chem. Soc., Chem. Commun., 1979, 851 DOI: 10.1039/C39790000851
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