In a process which involves a [1,5] silyl migration from nitrogen to oxygen, treatment of (Me3Si)2-NPMe2 with hexafluoroacetone or acetone itself affords the P–C bonded phosphine imines Me3SiN![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
PMe2[CR2-(OSiMe3)](R = CF3 or Me).
R. H. Neilson and D. W. Goebel, J. Chem. Soc., Chem. Commun., 1979, 769 DOI: 10.1039/C39790000769
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