The product from the reaction of hydroxylamine with diphenylphosphinic chloride (1) in benzene is O-(diphenylphosphinyl)hydroxylamine (3) rather than N-(diphenylphosphinyl)hydroxylamine (2); it forms an N-acetyl derivative (4) with acetic anhydride and condenses with acetone to give O-(diphenylphosphinyl)acetoxime (5).
M. J. P. Harger, J. Chem. Soc., Chem. Commun., 1979, 768 DOI: 10.1039/C39790000768
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