Issue 3, 1979

Synthetic access to α-substituted prop-2-ynylamines and α-acetylenic amino acids via the t-butyl N-trimethylsilylprop-2-ynylcarbamate dianion

Abstract

The dianion derived from t-butyl N-trimethyl-silylprop-2-ynycarbamate undergoes alkylation and carboxylation at the propynylic position, leading to derivatives of acetylenic amines and amino acids.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 119-120

Synthetic access to α-substituted prop-2-ynylamines and α-acetylenic amino acids via the t-butyl N-trimethylsilylprop-2-ynylcarbamate dianion

B. W. Metcalf and P. Casara, J. Chem. Soc., Chem. Commun., 1979, 119 DOI: 10.1039/C39790000119

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