Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 21st October 2020 from 07:00 AM to 07:00 PM (BST).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 9, 1978
Previous Article Next Article

Fluorination with xenon difluoride. Part 18. Reactivity of diphenyl sulphide and substituted thiochromanones

Abstract

The fluorination of diphenyl sulphide with 1 mol. equiv. of xenon difluoride resulted in formation of diphenyl sulphoxide, while reaction with 2 mol. equiv. of xenon difluoride gave diphenyl sulphone after hydrolysis. Reaction with 3-bromothiochroman-4-one resulted in the formation of 3-bromothiochromen-4-one, while fluorination of 3,3-dibromothiochroman-4-one yielded 3,3-dibromo-2-fluorothiochroman-4-one. The formation of di- and tetrafluoropersulphuranes, which were not isolated, is suggested.

Back to tab navigation

Article information


J. Chem. Soc., Perkin Trans. 1, 1978, 965-967
Article type
Paper

Fluorination with xenon difluoride. Part 18. Reactivity of diphenyl sulphide and substituted thiochromanones

M. Zupan and B. Zajc, J. Chem. Soc., Perkin Trans. 1, 1978, 965
DOI: 10.1039/P19780000965

Search articles by author

Spotlight

Advertisements