The title compounds give in unimolecular solvolyses different mixtures of 3-substituted-Δ4- and 5-substituted-Δ3-products probably via two distinct allylic carbonium ions. Bimolecular substitution and configurational inversion occur when the title compounds are treated with sodium azide-hexamethylphosphoramide.
G. Ortar, M. P. Paradisi, E. Morera and A. Romeo, J. Chem. Soc., Perkin Trans. 1, 1978, 4 DOI: 10.1039/P19780000004
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