Deuterium labelling is used to show that disproportionation of 10-methylacridinium iodide involves transfer of a hydride ion from the 9-position of the pseudo-base form of the compound to the 9-position of the 10-methylacridinium ion. Mass spectrometric fragmentations of some acridine and acridan derivatives have been elucidated with the aid of deuterium-labelled compounds.
J. Clark and M. Bakavoli, J. Chem. Soc., Perkin Trans. 1, 1977, 1966 DOI: 10.1039/P19770001966
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