The reaction of [{(CO)4Mn–S–SnMe3}2] with iodine affords [Mn4S4(CO)15], the crystal structure of which shows that dimerization and rearrangement have occurred during the oxidation.
V. Küllmer, E. Röttinger and H. Vahrenkamp, J. Chem. Soc., Chem. Commun., 1977, 782 DOI: 10.1039/C39770000782
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