Issue 21, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Hydrogen reduction of co-ordinated carbon monosulphide in [IrH(CS)(PPh3)3] to the methanethiolato-ligand and an iridium thioformyl compound [Ir(CHS)Cl2(CO)(PPh3)2]

Warren R. Roper  and  Keith G. Town  

Abstract

[IrH(CS)(PPh3)3] reacts with 2 equiv. of H2 to give [IrH2(SMe)(PPh3)3], and further reaction with HCl releases MeSH and forms [IrH2Cl(PPh3)3]; a thioformyl complex is a likely intermediate in this process and a stable example of such a compound is [Ir(CHS)Cl2(CO)(PPh3)2] from [IrCl2(CS)(CO)(PPh3)2]+ and NaBH4.

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Article information

DOI
https://doi.org/10.1039/C39770000781
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 781-782

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Hydrogen reduction of co-ordinated carbon monosulphide in [IrH(CS)(PPh3)3] to the methanethiolato-ligand and an iridium thioformyl compound [Ir(CHS)Cl2(CO)(PPh3)2]

W. R. Roper and K. G. Town, J. Chem. Soc., Chem. Commun., 1977, 781 DOI: 10.1039/C39770000781

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