Issue 15, 1977

Complex C.I.D.N.P. effects in the rearrangement of O-sulphinylated oximes

Abstract

Enhanced polarisations of several nuclei suggest that the thermal rearrangement of R1R2C[double bond, length half m-dash]N–OS-(O)R3 to sulphonyl imine proceeds partly by a recombination of geminate radical pairs and partly by the scavenging of escaped radicals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 540-542

Complex C.I.D.N.P. effects in the rearrangement of O-sulphinylated oximes

C. Brown, R. F. Hudson and K. A. F. Record, J. Chem. Soc., Chem. Commun., 1977, 540 DOI: 10.1039/C39770000540

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