Single crystal X-ray studies of iodine trifluoride dioxide have shown that the compound exists as a dimeric species in the crystalline state; the dimers are centrosymmetric with oxygen bridges and trans equatorial terminal oxygens.
L. E. Smart, J. Chem. Soc., Chem. Commun., 1977, 519 DOI: 10.1039/C39770000519
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