Copper(I) bis(trimethylsilyl)amide deoxygenates carbon dioxide in the presence of an added ligand to produce hexamethyldisiloxane and a copper(I) isocyanate complex which is converted into an alkyl isocyanate by treatment with an alkyl iodide.
T. Tsuda, H. Washita and T. Saegusa, J. Chem. Soc., Chem. Commun., 1977, 468 DOI: 10.1039/C39770000468
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