Issue 10, 1977

Stereoselectivity and carbon-14 isotope effect in methyl group transfer from s-butyldimethylsulphonium to para-thiocresolate ion

Abstract

The large rate-difference, observed in transfer of the prochiral methyl groups from (RS)-s-butyldimethylsulphonium p-toluenesulphonate (1) to p-thiocresolate, is attributed, by stereospecific 14C-labelling, to the compound operation of a small diastereotopic selectivity (< 4%) and a large isotope effect.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 355-356

Stereoselectivity and carbon-14 isotope effect in methyl group transfer from s-butyldimethylsulphonium to para-thiocresolate ion

G. Grue-Sørensen, A. Kjær and E. Wieczorkowska, J. Chem. Soc., Chem. Commun., 1977, 355 DOI: 10.1039/C39770000355

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