A crystallographic study of [(Ph3P)2Pt(N2O2)] shows that the two NO groups are coupled via the nitrogen atoms, forming a cis-hyponitrite ligand, which bonds to platinum through the oxygen atoms to give a [graphic omitted] ring.
S. Bhaduri, B. F. G. Johnson, A. Pickard, P. R. Raithby, G. M. Sheldrick and C. I. Zuccaro, J. Chem. Soc., Chem. Commun., 1977, 354 DOI: 10.1039/C39770000354
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