Issue 8, 1977

Novel catalytic resolution and asymmetric transformation of α-dichloro(triethylenetetra-amine)cobalt(III) dichloride

Abstract

Reaction of racemic [α-(trien)CoCl2] Cl with α-amino-α-methylmalonic acid in refluxing methanol, in the presence of triethylamine and catalytic amounts of naturally occurring chiral acids, produces high optical yields of a single enantiomeric product.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 258-259

Novel catalytic resolution and asymmetric transformation of α-dichloro(triethylenetetra-amine)cobalt(III) dichloride

R. C. Job, J. Chem. Soc., Chem. Commun., 1977, 258 DOI: 10.1039/C39770000258

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