Issue 13, 1976

Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum

Abstract

The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a= 15.903(5), b= 13.297(2), c= 12.925(2)Å, Z= 8. Mo–As is 2.533(2), and the Mo–C(alkyl) 2.35(1)Å. The η5-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1193-1195

Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum

P. D. Brotherton, C. L. Raston, A. H. White and S. B. Wild, J. Chem. Soc., Dalton Trans., 1976, 1193 DOI: 10.1039/DT9760001193

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements