Issue 13, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Photochemistry of some binuclear carbonyl compounds of manganese, rhenium, molybdenum, and tungsten, and of some related pentacarbonylmetal halides in n-donor solvents

David M. Allen,   Alan Cox,   Terence J. Kemp,   Qaisar Sultana  and  Richard B. Pitts  

Abstract

On irradiation in solvents of high donicity, the binuclear carbonyl compounds [M2(CO)10](M = Mn or Re) and [{M(η-C5H5)(CO)3}2](M = MO or W) undergo efficient photoheterolysis leading to a metal carbonyl anion; related carbonylmetal halides [M(CO)5X](M = Mn or Re, X = Cl, Br, or I) on similar treatment also give rise to the corresponding carbonyl anion.

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Article information

DOI
https://doi.org/10.1039/DT9760001189
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1189-1193

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Photochemistry of some binuclear carbonyl compounds of manganese, rhenium, molybdenum, and tungsten, and of some related pentacarbonylmetal halides in n-donor solvents

D. M. Allen, A. Cox, T. J. Kemp, Q. Sultana and R. B. Pitts, J. Chem. Soc., Dalton Trans., 1976, 1189 DOI: 10.1039/DT9760001189

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