Issue 13, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Nuclear magnetic resonance measurement of sulphur inversion barriers in mer-tris[bis(trimethylsilylmethyl) sulphide]trichloro-rhodium(III) and -iridium(III)

Edward W. Abel,   Graham W. Farrow  and  Keith G. Orrell  

Abstract

Variable-temperature 1H n.m.r. studies of mer-[RhCl3{S(CH2SiMe3)2}3] and mer-[IrCl3{S(CH2SiMe3)2}3] have yielded slightly different sulphur inversion barriers for the two different sulphide ligand environments in these complexes. In both complexes the barrier is somewhat lower for the sulphide ligand trans to chloride.

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Article information

DOI
https://doi.org/10.1039/DT9760001160
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1160-1163

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Nuclear magnetic resonance measurement of sulphur inversion barriers in mer-tris[bis(trimethylsilylmethyl) sulphide]trichloro-rhodium(III) and -iridium(III)

E. W. Abel, G. W. Farrow and K. G. Orrell, J. Chem. Soc., Dalton Trans., 1976, 1160 DOI: 10.1039/DT9760001160

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