The reactions of rhenium pentacarbonyl halides with a large excess of cyanide ion in aqueous methanolic solution follow a kinetic pattern characteristic of consecutive first-order processes [equation (i)]. Rate laws and kinetic [Re(CO)5X] [graphic omitted] [Re(CN)(CO)4X]– [graphic omitted] [RE(CN)2(CO)4]–(i) parameters are reported for these reactions, with X = Cl, Br, or I.
M. J. Blandamer, J. Burgess, S. J. Cartwright and M. Dupree, J. Chem. Soc., Dalton Trans., 1976, 1158 DOI: 10.1039/DT9760001158
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