The epoxidation of small to medium ring cyclic allylic alcohols with ButOOH–[VO(acac)2](acacH = pentane-2,4-dione) produces syn-epoxy alcohols with high stereoselectivity and in high yields.
T. Itoh, K. Kaneda and S. Teranishi, J. Chem. Soc., Chem. Commun., 1976, 421b DOI: 10.1039/C3976000421B
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