On direct photoisomerization of cyclo-octene, a trans : cis photostationary ratio of 49 : 51 was observed, which is anomalously high for a strained cycloalkene, whereas the trans : cis ratios on toluene photosensitization in the liquid and vapour phase were 5 : 95 and 13 : 87, respectively.
Y. Inoue, S. Takamuku and H. Sakurai, J. Chem. Soc., Chem. Commun., 1976, 423 DOI: 10.1039/C39760000423
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