Flash thermolysis of the trimethylsilyl ester (1) gives rise to enol ethers (3) and (5) whose formation is best explained via the strained bridgehead enol ether (2).
R. Bloch, F. Boivin and M. Bortolussi, J. Chem. Soc., Chem. Commun., 1976, 371 DOI: 10.1039/C39760000371
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