X-Ray analysis of µ-(isopropylamino)-µ-(propanone oximato)-bis(tricarbonyliron)(Fe–Fe), the main product of the reaction between [Fe3(CO)12] and 2-nitropropane, shows an unusual structure with an Fe–N–O–Fe ring, which can be related to the nature of novel intermediates in the reduction of nitro-compounds by iron carbonyls.
S. Aime, G. Gervasio, L. Milone, R. Rossetti and P. L. Stanghellini, J. Chem. Soc., Chem. Commun., 1976, 370 DOI: 10.1039/C39760000370
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