SCHEDULED MAINTENANCE
Hydrogenation of butadiene with HD over MoS2 gives two geometrical isomers, [3-2H1]but-1-ene and [4-2H1]but-1-ene; the ratio of the two isomers agrees strictly with the isotope effect for the overall reaction rates with H2 and D2.
T. Okuhara and K. Tanaka, J. Chem. Soc., Chem. Commun., 1976, 199 DOI: 10.1039/C39760000199
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