The dioxopiperazines resulting from thermal degradation of several actinomycins were identified by g.l.c. comparison with synthetic compounds, providing a convenient approach to amino-acid sequence determination. In a comparison of relative yields of various dioxopiperazines, different degradative pathways were apparent at different temperatures.
A. B. Mauger, J. Chem. Soc., Perkin Trans. 1, 1975, 1320 DOI: 10.1039/P19750001320
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