The minor products of the reaction of chlorosulphonyl isocyanate with a hex-2-enopyranoside in ether and in acetonitrile include a 3-alkoxycarbonylamino-3-deoxy-allal, 2-(D-glycero-1,2-diacetoxyethyl)furan, two hex-2-enopyranosylamines, and two C–C linked disaccharide derivatives. Reaction mechanisms are discussed.
R. H. Hall, A. Jordaan and O. G. de Villiers, J. Chem. Soc., Perkin Trans. 1, 1975, 626 DOI: 10.1039/P19750000626
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