SCHEDULED MAINTENANCE
We have prepared and characterised the unstable compound silylsulphinylamine, SiH3NSO, and report its vibrational, electronic, photoelectron, and n.m.r. spectra. Electron diffraction studies show that the skeleton is bent at nitrogen and at sulphur, has an unusually long Si–N bond, and is non-planar.
S. Cradock, E. A. V. Ebsworth, G. D. Meikle and D. W. H. Rankin, J. Chem. Soc., Dalton Trans., 1975, 805 DOI: 10.1039/DT9750000805
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