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The reactions of palladium atoms with olefins have been studied by low-temperature i.r. spectroscopy and the most stable compounds observed, bis(cyclo-octa-1,5-diene)palladium and tris(bicyclo[2.2.1]heptene)-palladium have been prepared from palladium atoms on a gram scale.
R. M. Atkins, R. Mackenzie, P. L. Timms and T. W. Turney, J. Chem. Soc., Chem. Commun., 1975, 764a DOI: 10.1039/C3975000764A
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