Issue 18, 1975

X-Ray structure of the hexa(µ2-arenethiolato-)tetra(arenethiolato)tetracobaltate(II) dianion, [(CoSPh)42-SPh)6]2–, a new tetrahedral tetracobalt thiolate cluster

Abstract

The unique molecular cluster complex [(CoSPh)4(µ2-SPh)6]2–(Me4N+ cation) contains an approximately Td Co4S10 core, the clustering of four tetrahedral {CoII-(µ2-SPh)3(SPh)} co-ordination units being a consequence of ligand bridging, not metal–metal bonding.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 762-763

X-Ray structure of the hexa(µ2-arenethiolato-)tetra(arenethiolato)tetracobaltate(II) dianion, [(CoSPh)42-SPh)6]2–, a new tetrahedral tetracobalt thiolate cluster

I. G. Dance and J. C. Calabrese, J. Chem. Soc., Chem. Commun., 1975, 762 DOI: 10.1039/C39750000762

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