Photoinduced insertion of tungsten into methanol giving a tungsten-methyl derivative
Abstract
Photolysis of [(η-C5H5)2WH2] in methanol gives the compounds [(η-C5H5)2WH(OMe)] and [(η-C5H5)2W(Me)(OMe)]; tungstenocene is proposed as an intermediate.
Photolysis of [(η-C5H5)2WH2] in methanol gives the compounds [(η-C5H5)2WH(OMe)] and [(η-C5H5)2W(Me)(OMe)]; tungstenocene is proposed as an intermediate.
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L. Farrugia and M. L. H. Green, J. Chem. Soc., Chem. Commun., 1975, 416b DOI: 10.1039/C3975000416B
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