Reduction of co-ordinated nitriles with BH4–, and Michael addition of a carbanion to co-ordinated acrylonitrile both occur more than 104 fold faster than the same reactions for the unco-ordinated nitriles.
I. I. Creaser and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1975, 974 DOI: 10.1039/C39750000974
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